5-Cyclo­hexyl-2-(4-methyl­phen­yl)-3-methyl­sulfinyl-1-benzofuran

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Uk Lee
چکیده

In the title compound, C(22)H(24)O(2)S, the cyclo-hexyl ring adopts a chair conformation. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions. In the methyl-sulfinyl group, the methyl group and S atom are disordered over two sets of sites, with site-occupancy factors of 0.58 (3) and 0.42 (3). In the ring of the 4-methyl-phenyl group, the four C atoms are disordered over two sets of sites, with site-occupancy factors of 0.858 (5) and 0.142 (5).

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منابع مشابه

5-Bromo-2-(4-methyl­phen­yl)-3-methyl­sulfinyl-1-benzofuran

In the title compound, C16H13BrO2S, the 4-methyl-phenyl ring makes a dihedral angle of 29.58 (7)° with the mean plane [r.m.s. deviation = 0.007 (2) Å] of the benzofuran fragment. In the crystal, the molecules are linked by pairs of C-H⋯O hydrogen bonds into centrosymmetric dimers.

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5-Cyclo­hexyl-2-(4-fluoro­phen­yl)-3-methyl­sulfinyl-1-benzofuran

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5-Bromo-7-methyl-2-(4-methyl­phen­yl)-3-methyl­sulfinyl-1-benzofuran

In the title compound, C17H15BrO2S, the 4-methyl-phenyl ring makes a dihedral angle of 14.46 (5)° with the mean plane [r.m.s. deviation = 0.005 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by pairs of Br⋯O contacts [3.151 (2) Å] into centrosymmetric dimers.

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5-Cyclo­hexyl-2-(3-fluoro­phen­yl)-3-methyl­sulfinyl-1-benzofuran

In the title compound, C(21)H(21)FO(2)S, the cyclo-hexyl ring adopts a chair conformation. The 3-fluoro-phenyl ring makes a dihedral angle of 38.38 (6)° with the mean plane [r.m.s. deviation = 0.010 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds.

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5-Fluoro-2-(4-methyl­phen­yl)-3-methyl­sulfinyl-1-benzofuran

In the title compound, C16H13FO2S, the 4-methyl-phenyl ring makes a dihedral angle of 29.53 (4)° with the mean plane of the benzofuran fragment [r.m.s. deviation = 0.004 (1) Å]. In the crystal, mol-ecules are linked by pairs of weak C-H⋯O hydrogen bonds, forming inversion dimers that stack along the a axis.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012